Journal
CHEMICAL ENGINEERING JOURNAL
Volume 171, Issue 3, Pages 1469-1476Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2011.05.081
Keywords
Gas permeability; Selectivity; Polyimide; Polysulfone; ZSM-5
Categories
Funding
- National Iranian Oil Refining and Distribution Co. (NIORDC)
Ask authors/readers for more resources
In this study the gas separation performance of polyimide/polysulfone (Pl/PSF) mixed matrix membranes filled with zeolite ZSM-5 particles is investigated. The membranes are prepared by solution-casting method and utilized to determine the permeation rates of N-2, O-2, CO2 and CH4 through pure polymers as well as composite membranes. The membranes are characterized by SEM, TGA and FTIR. The effects of polymers ratio and weight fraction of zeolite on permeation and selectivity of the gases are discussed. Polymers ratio in the mixed matrix have assumed values of 100% PSF, 70/30 (PSF/PI), 50/50,30/70 and 100% PI while ZSM-5 loadings are varied between 0 and 20 wt.%. SEM results showed that fabricated membranes have homogeneous structure. With pure polyimide membrane, O-2 permeability increased from 0.69 Barrer for membrane without zeolite up to 0.73 and 0.89 Barrer for membranes with 10% and 20% zeolite, respectively. Within blended matrices, the minimum permeability (maximum selectivity) and the most homogeneous matrix structure were related to the matrix with 50/50 weight percent of two polymers. (C) 2011 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available