Journal
CHEMICAL ENGINEERING JOURNAL
Volume 172, Issue 1, Pages 37-46Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2011.05.015
Keywords
Spectroscopic analyses; Wastewater; Clays; Heavy metals; Adsorption isotherm
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The present work aimed to achieve mineralogical and spectroscopic characterization of the Late Cretaceous clays of Aleg formation (Coniacian-Lower Campanian system), Tunisia, for the removal of several toxic metals in aqueous system. The collected clay samples were first characterized by different techniques including X-ray fluorescence (XRF), thermal analysis (TG/TDA), X-ray diffraction (XRD). Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). Results showed that the natural clay samples are mainly composed of silica, alumina, iron, calcium and magnesium oxides. The sorbents are mainly mesoporous materials with modest specific surface area of <71 m(2)/g. Then, the possible use of the studied clay samples as adsorbents for the removal of Pb(II), Cd(II), Cu(II) and Zn(II) from aqueous solutions was evaluated. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models were used to simulate the equilibrium data. The maximum adsorption capacity varied between 6.78 and 131.58 mg/g, showing much higher removal efficiency than the relevant previous studies. Langmuir isotherms showed the best fitting to the experimental data. Among the studied clay samples, the amount of calcium carbonates was the most influencing parameter for heavy metal removal. The results suggest that the studied clay samples can be effectively used for the treatment of contaminated wastewaters. (C) 2011 Elsevier B.V. All rights reserved.
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