Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 81, Pages 11419-11422Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06768f
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Funding
- 973 Program [2015CB856600]
- NSFC [21332002]
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Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp(3))-Si bond formation. The reaction, which uses readily available N-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(ii) and Cu(i) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(ii) carbene migratory insertion/reductive elimination mechanism is proposed.
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