Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 76, Pages 10683-10686Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04736g
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Funding
- European Research Council under the European Union's Horizon 2020 Research and Innovation Programme [648295]
- Deutsche Forschungsgemeinschaft [PO 1602/5-1]
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Carbide clusterfullerene DyYTiC@C-80-I-h with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C-80 are compared to those of DySc2N@C-80 and the influence of the central atom in the endohedral cluster is analyzed.
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