Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 71, Pages 9909-9912Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc05256e
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The reactivity of fluoroalkylselenotoluenesulfonates with unsaturated substrates is explored herein. The direct activation of these shelf-stable reagents under visible light allows the double functionalisation of alkenes or alkynes efficiently, leading to a wide range of beta-fluoroalkylselenolated sulfones. Mechanistic investigations have been undertaken supporting the formation of radical intermediates.
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