4.7 Article

Enabling shape memory and healable effects in a conjugated polymer by incorporating siloxane via dynamic imine bond

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 72, Pages 10092-10095

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc05410j

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Funding

  1. Singapore National Research Foundation [R279-000-444-281, R279-000-483-281]
  2. National University of Singapore [R279-000-482-133]

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A conjugated polymer of poly(fluorene-co-benzothiadiazole) (PFBT) was modified by a soft segment of poly(dimethylsiloxane) (PDMS) to yield a copolymer via dynamic imine bonds. The copolymer was casted as a free-standing film, which was intrinsically flexible, stretchable, and showed tunable shape memory, healable and degradable effects.

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