4.7 Article

Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 68, Pages 9450-9453

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04287j

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Funding

  1. Russian Science Foundation [17-43-00001] Funding Source: Russian Science Foundation

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Platinum-[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue LED) enabling the conversion of a range of terminal and internal alkynes to respective vinyl silanes in excellent yields.

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