4.7 Article

Selective synthesis of [7]- and [8]cycloparaphenylenes

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 8, Pages 954-956

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48683d

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Funding

  1. JSPS [220GR049]
  2. International Research Training Group Munster/Nagoya
  3. World Premier International Research Center (WPI) Initiative, Japan

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Cycloparaphenylenes (CPPs) are a remarkable class of hoop-shaped conjugated macrocycles with inimitable properties. Herein we describe a divergent synthesis of [7]CPP and [8]CPP. Furthermore we present the first crystal structure of [7]CPP. Thus, we have now established the size-selective synthesis of [n]CPP (n = 7-16) in a uniformed cyclohexane-based method.

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