4.7 Article

A dye-sensitized Pt@UiO-66(Zr) metal-organic framework for visible-light photocatalytic hydrogen production

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 53, Pages 7063-7066

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01086h

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Funding

  1. National Natural Science Foundation of China [NSFC-YN U1033603, 21063016]
  2. Program for Innovative Research Teams (in Science and Technology) in the University of Yunnan Province (IRTSTYN)

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A stable photoactive metal-organic framework UiO-66(Zr) sensitized by adsorbed or directly added rhodamine B dye exhibited photo-catalytic activity for hydrogen evolution under visible-light illumination (lambda >= 420 nm). Using Pt as a co-catalyst, the adsorbed and directly added dye extremely enhanced the photocatalytic activity to 30 and 26 times the value afforded by bare Pt@ UiO-66(Zr), respectively.

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