Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 19, Pages 2431-2433Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49385g
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Funding
- National Research Foundation of South Africa [76226]
- Fulbright Scholar Program
- DOE [DE-FG02-13ER16370]
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The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated.
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