Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 4, Pages 448-450Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47926a
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- Institute for Basic Science (IBS)
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Cu(II)-catalyzed cyanation of aryl iodides has been developed using DMF and ammonium bicarbonate as the combined source of cyanide. It is assumed that copper is involved both in the generation of CN units from DMF-ammonia and in the cyanation of aryl halides. A range of electron-rich and fused (hetero)aryl iodides underwent cyanation resulting in moderate to good yields.
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