Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 89, Pages 13825-13828Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05665e
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Funding
- National Natural Science Foundation of China [51203058, 51373064, 51173061, 21074043]
- Frontiers of Science and Interdisciplinary Innovation Project of Jilin University [450060481015]
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A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g(-1) of CO2, 9.9 mg g(-1) of H-2, and 11.5 mg g(-1) of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N-2 and CH4.
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