4.7 Article

Enhanced CO2 sorption and selectivity by functionalization of a NbO-type metal-organic framework with polarized benzothiadiazole moieties

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 81, Pages 12105-12108

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05833j

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Funding

  1. National Natural Science Foundation of China [21301156]
  2. Open Research Fund of Top Key Discipline of Chemistry in Zhejiang Provincial Colleges
  3. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials [ZJHX201313]
  4. Welch Foundation [AX-1730]

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A new NbO-type metal-organic framework ZJNU-40 incorporating highly polarized benzothiadiazole moieties exhibits a high CO2 uptake of 108 cm(3) g(-1) at 296 K and 1 atm, as well as good adsorption selectivities of CO2 over CH4 and N-2 at room temperature, which is superior to that of the analogous MOF NOTT-101.

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