Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 62, Pages 8495-8498Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01783h
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Funding
- National Natural Science Foundation of China [51203058, 51173061, 21074043]
- Interdisciplinary Innovation Project of Jilin University [450060481015]
- Frontiers of Science
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A new metalloporphyrin-based conjugated microporous polymer, NiP-CMP, was constructed via a homo-coupling polymerization reaction. NiP-CMP possesses a high BET surface area of over 2600 m(2) g(-1), a large pore volume of 2.288 cm(3) g(-1), good stability, and displays excellent guest uptake of 202 wt% in iodine vapour. We also highlight that the polymer exhibits outstanding performance for the reversible adsorption of iodine in solution.
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