4.7 Article

Nickel-catalysed carboxylation of organoboronates

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 59, Pages 8010-8013

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03650f

Keywords

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Funding

  1. ERC (Advanced Researcher award-FUNCAT, CO2Chem)
  2. King Saud University

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A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.

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