Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 86, Pages 13052-13055Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03644a
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Funding
- MEXT, Japan
- JSPS
- Grants-in-Aid for Scientific Research [13J00320] Funding Source: KAKEN
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The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.
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