4.7 Article

Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 86, Pages 13052-13055

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03644a

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Funding

  1. MEXT, Japan
  2. JSPS
  3. Grants-in-Aid for Scientific Research [13J00320] Funding Source: KAKEN

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The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.

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