4.7 Article

Control of emission colour with N-heterocyclic carbene (NHC) ligands in phosphorescent three-coordinate Cu(I) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 54, Pages 7176-7179

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02037e

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Funding

  1. Universal Display Corporation
  2. National Science Foundation [CHE-1054910]
  3. University of Southern California Center for High-Performance Computing and Communications
  4. National Science Foundation CRIF Grant [1048807]

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A series of three phosphorescent mononuclear (NHC)-Cu(I) complexes were prepared and characterized. Photophysical properties were found to be largely controlled by the NHC ligand chromophore. Variation of the NHC ligand leads to emission colour tuning over 200 nm range from blue to red, and emission efficiencies of 0.16-0.80 in the solid state.

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