4.7 Article

Photocatalytic CO2 conversion over alkali modified TiO2 without loading noble metal cocatalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 78, Pages 11517-11519

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04848b

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Funding

  1. World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA), MEXT, Japan
  2. National Basic Research Program of China (973 Program) [2014CB239301]

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Surface modification of TiO2 with NaOH promoted the chemisorption, activation and photocatalytic CO2 reduction. An optimized loading amount of NaOH kept a good balance between CO2 chemisorption quantity and BET surface area of TiO2. This noble metal free method provides a simple pathway for effective multiple H+/e(-) CO2 photoreduction.

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