Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 95, Pages 14949-14952Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07648f
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Funding
- NSFC [21025103, 21371119, 21431004, 21401128]
- 973 Program [2014CB932102, 2012CB8217]
- [SSTC-12XD1406300]
- [14YF1401300]
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Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF-1 is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.
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