Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 61, Pages 8299-8302Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01757a
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The use of a masked diboron as a boron source in the presence of a Cu-N-heterocyclic carbene (NHC) catalyst enables alkyl-, aryl-, heteroatom- and silyl-substituted terminal alkynes to undergo a-selective formal hydroboration to give diverse branched alkenylboron compounds exclusively. Synthetic potential of this alpha-selective hydroboration has been demonstrated by total synthesis of pharmaceutically significant bexarotene and LG100268.
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