4.7 Article

Poly(3-alkylthiophene)s show unexpected second-order nonlinear optical response

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 21, Pages 2741-2743

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48099b

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Funding

  1. Scientific Research Fund Flanders (FWO)
  2. Onderzoeksfonds KU Leuven/Research Fund KU Leuven

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Regioregular poly(3-hexylthiophene)s with chain lengths varying from 5 to 100 monomers are synthesized. Poly(3-hexylthiophene) s show in solution an unexpectedly significant second-order nonlinear optical response. The increase in transition dipole moment upon oligomerisation causes the significant second-order nonlinear optical response.

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