Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 65, Pages 9115-9118Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04100c
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Funding
- National Basic Research Program of China [2012CB821706, 2013CB834803]
- National Natural Science Foundation of China [21171114, 91222202]
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A tetradecanuclear copper(I) cluster compound, namely [Cu6L3(Cu2I2)Cu6L3] (H2L = 3,5-bis((3,5-dimethyl-pyrazol-4-yl)methyl)-2,6-dimethyl-pyridine), is synthesized. The high thermal stability, well-resolved blue/red dual emissions and two-way luminescent thermochromism warrant its self-calibrated temperature sensing ability, covering a wide range (120-450 K). These promising results are supported by combined structural, spectral and computational studies.
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