4.7 Article

Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 29, Pages 3874-3877

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00688g

Keywords

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Funding

  1. Natural Science Foundation of China [21302099]
  2. Natural Science Foundation of Jiangsu Province [BK2012449]
  3. Natural Science Foundation of Jiangsu Provincial Colleges and Universities [12KJB150014]
  4. Scientific Research Start-up Foundation of Nanjing Normal University [2011103XGQ0250]
  5. Priority Academic Program Development of Jiangsu Higher Education Institutions

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The first highly effective iron-catalyzed carbonylative Suzuki reaction has been developed. Substrates with electron-donating or electron-withdrawing functionality, ortho-substitution, as well as active groups proceeded smoothly, affording desired products in high yields. This protocol is economical, environmentally benign and practical for the synthesis of biaryl ketones.

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