Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 85, Pages 12915-12918Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05692b
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Funding
- NSFC [21325208, 21302178, 21172209, 21361140372]
- 973 Program [2012CB215305]
- SRFDP [20123402110051]
- FRFCU [WK2060190025]
- CAS [KJCX2-EW-J02]
- Fok Ying Tung Education Foundation, China Postdoctoral Science Fundation [2013M540516]
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A new copper-catalyzed trifluoromethylarylation reaction of alkynes has been developed. The transformation represents the first example of endo-type carbotrifluoromethylation of unsaturated carbon-carbon bonds and provides efficient access to a variety of CF3-substituted dihydronaphthalenes and chromenes.
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