4.7 Article

A highly permeable and selective amino-functionalized MOF CAU-1 membrane for CO2-N-2 separation

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 28, Pages 3699-3701

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00068d

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Funding

  1. Program for New Century Excellent Talents in University [NCET-10-0286]
  2. National Natural Science Foundation of China [21076029]

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A thin tubular CAU-1 membrane of 2-3 mu m exhibiting a high CO2 permeance of up to 1.34 x 10(-6) mol m(-2) s(-1) Pa-1 and a CO2-N-2 selectivity of 17.4-22.8 for CO2-N-2 mixtures was achieved, demonstrating for the first time that amino-functionalized MOF membranes can provide high CO2-N-2 selectivity and possess the potential for CO2 capture from flue gas.

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