4.7 Article

A sodium-enabled 'Pourbaix sensor': a three-input AND logic gate as a 'lab-on-a-molecule' for monitoring Na+, pH and pE

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 8, Pages 1009-1011

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48075e

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Funding

  1. University of Malta
  2. Strategic Educational Pathways Scholarship (Malta) program
  3. European Social Fund (ESF) under Operational Programme II - Cohesion Policy
  4. European Cooperation in Science and Technology [COST CM1005]

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A novel supramolecular three-input AND logic gate is demonstrated as a 'lab-on-a-molecule' for monitoring the Na+, pH and pE levels in solution by communicating a fluorescence signal. The fluorescence signal is modulated by three photoinduced electron transfer reactions that are controlled by an unprecedented combination of two cation binding events and one redox reaction.

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