Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 7, Pages 839-841Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47154c
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- Funding Program for Next Generation World-Leading Researchers (NEXT Program) [GR-003]
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Ligation of 2,6-diphenylbenzenethiol (DppSH) onto Au clusters stabilized by poly(N-vinyl-2-pyrrolidone) and subsequent core etching yielded a single cluster Au-25(SDpp)(11). High-energy X-ray diffraction measurement showed that Au-25 constitutes a core in Au-25(SDpp)(11). We propose a bi-icosahedral Au-25 core whose 22 Au surface atoms are capped directly by 11 bulky arenethiolates.
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