Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 100, Pages 15995-15998Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06159d
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Funding
- EPSRC [EP/H00338X/2]
- Christian Doppler Research Association (Austrian Federal Ministry of Science, Research and Economy)
- OMV Group
- Christian Doppler Research Association (National Foundation for Research, Technology and Development)
- Engineering and Physical Sciences Research Council [EP/H00338X/2, 1235151] Funding Source: researchfish
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The electrocatalytic proton reduction activity of a Ni bis(diphosphine) (NiP) and a cobaloxime (CoP) catalyst has been studied in water in the presence of the gaseous inhibitors O-2 and CO. CoP shows an appreciable tolerance towards O-2, but its activity suffers severely in the presence of CO. In contrast, NiP is strongly inhibited by O-2, but produces H-2 under high CO concentrations.
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