Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 74, Pages 10864-10867Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04773g
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21272028, 21202013]
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
- Changzhou University
Ask authors/readers for more resources
The tert-butyl hydroperoxide (TBHP) promoted sequential silylation and aromatisation of isonitriles was developed, where the silyl group was regioselectively installed at the 6-position of phenanthridines. This procedure tolerates a series of functional groups, such as fluoro, chloro, acetyl, methoxy carbonyl, cyano and trifluoromethyl. The addition of a silyl radical to the isonitrile followed by an intramolecular aromatic cyclization was involved in this transformation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available