4.7 Article

n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp(3))-H with anilines under metal-free conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 59, Pages 8006-8009

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01189a

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Funding

  1. National Science Foundation of China [21372095, 21202057, 21172092]
  2. National Science Foundation of Anhui Province [1408085MB34]
  3. Department of Education, Anhui Province [KJ2013B246]

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A novel and efficient n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp(3))-H with anilines to form N-substituted anilines under metal-free conditions has been developed.

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