4.7 Article

The unprecedented catalytic activity of alkanolamine CO2 scrubbers in the cycloaddition of CO2 and oxiranes: a DFT endorsed study

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 89, Pages 13664-13667

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04195j

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Funding

  1. National Research Foundation of Korea [NRF 2012-001507, 2013M3A6B1078877]
  2. Pusan National University (PNU) post-doc program
  3. NRF [2013R1A1A2058739]
  4. National Research Foundation of Korea [2013M3A6B1078877, 2013R1A1A2058739] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A novel application of alkanolamines, widely employed as CO2 scrubbers in catalyzing the insertion of CO2 into epoxides generating cyclic carbonates in excellent yield and selectivity via the synergistic activity of hydroxyl and amine groups, is unravelled along with computational studies.

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