Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 67, Pages 9550-9553Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03920c
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Funding
- National Science Foundation of China [21272087, 21202053, 21232003]
- National Basic Research Program of China [2011CB808603]
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The Pd/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 985% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.
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