Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 44, Pages 5871-5873Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49143a
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Funding
- US National Science Foundation [CHE-1112035]
- NSF [CHE-1048367, CHE-1229234]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1229234] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1112035] Funding Source: National Science Foundation
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A series of five-coordinate M-II-semiquinonate (M = Fe, Mn, Co) complexes were synthesized and characterized, including the first example of a mononuclear Fe-II-semiquinonate. Intermediates were observed in the reactions of M-II-phenSQ (M = Fe, Co) with O-2. Evidence for the relevance of these intermediates to the intradiol catechol dioxygenases was obtained by characterization of the oxidized semiquinone-derived product, muconic anhydride, resulting from the reaction of [PhTt(tBu)] Co-II(3,5-DBSQ) with O-2.
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