Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 27, Pages 3612-3615Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00690a
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Funding
- Major Research Plan Breeding and Transmutation of Nuclear Fuel in Advanced Nuclear Fission Energy System'' of the NSFC of China [91326202, 91126006]
- NSFC of China [21101157, 21201166, 11275219, 11105162, 21261140335]
- Strategic Priority Research Program'' of the Chinese Academy of Sciences [XDA030104]
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In situ assembly of a cucurbituril-based pseudorotaxane and a uranyl nitrate precursor under hydrothermal conditions affords the first actinide polyrotaxane with a unique 'dragon-like' twist, which is induced by the specific coordination pattern of uraniumand stabilized by hydrogen bonding between the eta(1)-mode carboxylate group and adjacent methylene moieties of CB[6].
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