Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 57, Pages 7621-7624Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02085e
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Funding
- National Basic Research Program of China [2010CB923402, 2013CB922102]
- NSF of Jiangsu Province of China [BK20130054]
- Graduate Innovation Fund of Jiangsu Province of China [0205Y511]
- Fundacao para a Ciencia e a Tecnologia (FCT, Portugal) [Pest-C/CTM/LA0011/2013]
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A layered erbium(III) phosphonate compound, [Er(notpH(4))(H2O)]ClO4 center dot 3H(2)O (1), in which the Er-III ion has a pseudo-D-5h symmetry exhibits field tunable multiple magnetic relaxation. The near-IR emission spectrum of 1, excited at 1064 nm (Nd:YAG laser), provides a direct probe of the crystal field splitting correlated to the magnetic data.
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