Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 26, Pages 3435-3438Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49850f
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Funding
- Liebig fellowship of the Fonds der Chemischen Industrie''
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The nucleophilicity of the substituents in iodobenzene pre-catalysts have a huge impact on product selectivity in iodine(III) triggered halogenations, steering the reactivity from solely carbocyclizations towards dihalogenations. Utilizing this catalyst-dependent reactivity a diastereo- and chemoselective dihalogenation method was established allowing the conversion of structurally and electronically diverse unsaturated compounds in excellent yields.
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