Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 8, Pages 1006-1008Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47002d
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Funding
- U.S. Department of Energy [FG02-10ER16170]
- U.S. National Science Foundation [CBET-1159882]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1159882] Funding Source: National Science Foundation
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The Ullmann reaction of bromobenzene, the simplest coupling reagent, to form biphenyl on a Cu surface proceeds via a highly mobile organometallic intermediate in which two phenyl groups extract and bind a single surface Cu atom.
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