Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 35, Pages 4551-4553Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00846d
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Funding
- National Science Foundation [CHE-1266323]
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The synthesis of the first stable, five-membered N,N'-diamidocarbenes (DACs), including a differentially N-substituted derivative, was achieved via the reduction of a geminal dichloride precursor using potassium. Key differences between the reactivity of the five-membered DACs and their six-membered congeners were observed, including an ability to insert into electron-rich C-H bonds.
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