Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 48, Pages 6326-6329Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46865h
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Funding
- National Science Foundation [CHE-0840505]
- University of California
- Helios Solar Energy Research Center
- Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, of the U.S. Department of Energy [DE-AC02-05CH11231]
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The compound [Co-2(mu-OH)(2)(OH2)(2)(DPFN)][NO3](4) is a molecular structural analog of proposed active sites of cobalt phosphate water oxidation catalysts. Computational studies on this system indicate feasible catalytic pathways to oxygen formation, despite the low electrocatalytic activity observed for [Co-2(mu-OH)(2)(OH2)(2)(DPFN)][NO3](4). Electrochemical and reactivity studies implicate the binding of phosphate to the dicobalt core, which may inhibit water oxidation catalysis.
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