4.7 Article

A mononuclear cobalt complex with an organic ligand acting as a precatalyst for efficient visible light-driven water oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 17, Pages 2167-2169

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48059c

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Funding

  1. National Natural Science Foundation of China [21173105, 21172098]
  2. Fundamental Research Funds for the Central Universities [zujbky-2013-50, lzujbky-2013-ct 02]

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N,N'-Bis(salicylidene)ethylenediaminecobalt(II) (1) has been investigated as a highly efficient water oxidation precatalyst with a TON of 854 at pH = 9.0, using [Ru(bpy)(3)](ClO4)(2) as a photosensitizer and Na2S2O8 as a sacrificial electron acceptor.

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