4.7 Article

Layered structures and nanosheets of pyrimidinethiolate coordination polymers

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 30, Pages 3955-3957

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00771a

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Funding

  1. EPSRC via Cambridge NanoDTC
  2. INDO-SWEDISH project

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We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators.

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