Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 1, Pages 16-28Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45518a
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Funding
- MEC [CTQ2010-16088/BQU]
- MECD
- European Research Council [321066]
- AGAUR [2009SGR47]
- ICIQ Foundation
- European Research Council (ERC) [321066] Funding Source: European Research Council (ERC)
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Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.
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