Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 63, Pages 8771-8774Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03491k
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Funding
- GlaxoSmithKline
- Singapore Economic Development Board [279-000-331-592]
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P450tol monooxygenase was discovered as a unique and highly enantioselective enzyme for asymmetric epoxidation of some terminal alkenes containing electron-withdrawing groups and benzylic hydroxylation of several ethylbenzenes giving the corresponding useful and valuable products, such as (R)-2- and 3-substituted styrene oxides, (S)-4-substituted styrene oxides, and (S)-benzylic alcohols, in high ee.
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