4.7 Article

Efficient CO2 capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 59, Pages 7933-7936

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01588f

Keywords

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Funding

  1. National Basic Research Program of China [2013CB733501]
  2. National Natural Science Foundation of China [91334203, 21176066]
  3. 111 Project of China [B08021]
  4. Fundamental Research Funds for the Central Universities of China
  5. U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division

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A porous triazine and carbazole bifunctionalized task-specific polymer has been synthesized via a facile Friedel-Crafts reaction. The resultant porous framework exhibits excellent CO2 uptake (18.0 wt%, 273 K and 1 bar) and good adsorption selectivity for CO2 over N-2.

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