4.7 Article

Red-luminescent biphosphine stabilized 'Cu12S6' cluster molecules

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 75, Pages 11043-11045

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04702h

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The synthesis, molecular structures and luminescence properties of two 'Cu12S6' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields (>= 48%) and good stability towards oxygen.

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