Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 5, Pages 578-580Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45958f
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Funding
- National Natural Science Foundation of China [21032007, 21172038]
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3-((Trifluoromethyl) thio)indoles can be synthesized by a palladium(II)-catalyzed reaction of 2-alkynylaniline with trifluoromethanesulfanylamide in the presence of bismuth(III) chloride. The presence of bismuth(III) chloride is crucial for the success of this transformation, which activates the trifluoromethanesulfanylamide during the reaction.
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