4.7 Article

Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple 'pseudo-fluid' model for a ball milling reaction

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 13, Pages 1585-1587

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47898j

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Funding

  1. Royal Society
  2. NSFC [21061005, 21241008]
  3. Hainan International Joint Project [KJHZ2013-18]

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Quantitative monitoring of a mechanochemical reaction by Raman spectroscopy leads to a surprisingly straightforward second-order kinetic model in which the rate is determined simply by the frequency of reactive collisions between reactant particles.

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