4.7 Article

B(C6F5)(3) promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 55, Pages 7243-7245

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01370k

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Funding

  1. NSERC of Canada
  2. award of a Canada Research Chair
  3. Fonds der Chemischen Industrie for a Chemiefonds scholarship
  4. Studienstiftung des deutschen Volkes

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The reactions of internal propargyl esters with B(C6F5)(3) provide access to stable zwitterionic 1,3-dioxolium compounds which are characterised by X-ray diffraction. These 6 pi-electron systems show no significant aromatic stabilisation.

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