4.7 Article

Photocatalytic chemoselective reduction of epoxides to alkenes along with formation of ketones in alcoholic suspensions of silver-loaded titanium(IV) oxide at room temperature without the use of reducing gases

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 35, Pages 4558-4560

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49340g

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [23560935]
  2. Faculty of Science and Engineering, Kinki University
  3. Japan Society for the Promotion of Science (JSPS)
  4. Grants-in-Aid for Scientific Research [13J07957, 26630415, 26289307, 12J09929, 23560935] Funding Source: KAKEN

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(2,3-Epoxypropyl) benzene was chemoselectively reduced to allylbenzene along with formation of ketones in alcoholic suspensions of a silver-loaded titanium(IV) oxide photocatalyst at room temperature under atmospheric pressure without the use of reducing gases, and various epoxides were also reduced to the corresponding alkenes.

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