Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 82, Pages 12293-12296Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05901h
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Funding
- University of Wisconsin
- NIH [R01GM088285]
- Chinese Scholarship Council
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Various highly substituted 2,3'-diindolylmethane heterocycles were prepared from propargylic alcohols and indole nucleophiles via a transition metal-catalyzed tandem indole annulation/arylation reaction for the first time. Among the metal catalysts we examined, the most economical copper(I) catalyst provided the highest efficiency. The indole nucleophiles could also be replaced by other electron-rich arenes or alcohols.
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